Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Identifieur interne : 000168 ( Main/Exploration ); précédent : 000167; suivant : 000169Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Auteurs : Assia Hajsalem [Tunisie] ; Sameh Aoun [France] ; Aurelien Planchat [France] ; Mohamed Rzaigui [Tunisie] ; Samah Akriche Toumi [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co2+ ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the
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DOI: 10.1107/S160053681400484X
PubMed: 24826091
PubMed Central: 3998553
Affiliations:
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type="wicri:Area/Main/Exploration">000168</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis[tris(phenanthroline-κ<sup>2</sup><italic>N</italic>,<italic>N</italic>′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate</title><author><name sortKey="Hajsalem, Assia" sort="Hajsalem, Assia" uniqKey="Hajsalem A" first="Assia" last="Hajsalem">Assia Hajsalem</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Aoun, Sameh" sort="Aoun, Sameh" uniqKey="Aoun S" first="Sameh" last="Aoun">Sameh Aoun</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Planchat, Aurelien" sort="Planchat, Aurelien" uniqKey="Planchat A" first="Aurelien" last="Planchat">Aurelien Planchat</name><affiliation wicri:level="1"><nlm:aff id="b">Laboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Toumi, Samah Akriche" sort="Toumi, Samah Akriche" uniqKey="Toumi S" first="Samah Akriche" last="Toumi">Samah Akriche Toumi</name><affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country></nlm:aff><country xml:lang="fr">Tunisie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2014">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>In the title hydrated salt, [Co(C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>)<sub>3</sub>]<sub>2</sub>[PVW<sub>11</sub>O<sub>40</sub>]·2H<sub>2</sub>O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO<sub>4</sub> group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co<sup>2+</sup> ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN<sub>6</sub> octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the <italic>c</italic>-axis direction.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>France</li><li>Tunisie</li></country></list><tree><country name="Tunisie"><noRegion><name sortKey="Hajsalem, Assia" sort="Hajsalem, Assia" uniqKey="Hajsalem A" first="Assia" last="Hajsalem">Assia Hajsalem</name></noRegion><name sortKey="Rzaigui, Mohamed" sort="Rzaigui, Mohamed" uniqKey="Rzaigui M" first="Mohamed" last="Rzaigui">Mohamed Rzaigui</name><name sortKey="Toumi, Samah Akriche" sort="Toumi, Samah Akriche" uniqKey="Toumi S" first="Samah Akriche" last="Toumi">Samah Akriche Toumi</name></country><country name="France"><noRegion><name sortKey="Aoun, Sameh" sort="Aoun, Sameh" uniqKey="Aoun S" first="Sameh" last="Aoun">Sameh Aoun</name></noRegion><name sortKey="Planchat, Aurelien" sort="Planchat, Aurelien" uniqKey="Planchat A" first="Aurelien" last="Planchat">Aurelien Planchat</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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